题名 | Recent advances in copper-catalysed radical-involved asymmetric 1,2-difunctionalization of alkenes |
作者 | |
通讯作者 | Liu,Xin Yuan |
共同第一作者 | Fang,Gui Chun; Gu,Qiang Shuai; Liu,Xin Yuan |
发表日期 | 2019-12-05
|
DOI | |
发表期刊 | |
ISSN | 0306-0012
|
EISSN | 1460-4744
|
卷号 | 49期号:1页码:32-48 |
摘要 | The radical-involved 1,2-difunctionalization of alkenes has developed into a robust tool for preparation of complex organic molecules. Despite significant advances in this area, the catalytic asymmetric version still remains a challenging task mainly due to the difficulty in the stereocontrol of the highly reactive radical intermediates. Recently, owing to the good single-electron transfer ability and coordination with chiral ligands of copper catalysts, remarkable achievements in radical-involved asymmetric alkene difunctionalization have been made via synergistic combination of copper and chiral ligands. This tutorial review highlights the recent progress in copper-catalysed radical-involved asymmetric 1,2-difunctionalization of alkenes and the mechanistic scenarios governing the stereocontrol, with an emphasis on utilization of chiral ligands. |
相关链接 | [Scopus记录] |
收录类别 | |
语种 | 英语
|
重要成果 | ESI高被引
|
学校署名 | 第一
; 通讯
|
资助项目 | Shenzhen Nobel Prize Scientists Laboratory Project[C17783101]
|
WOS研究方向 | Chemistry
|
WOS类目 | Chemistry, Multidisciplinary
|
WOS记录号 | WOS:000508005100002
|
出版者 | |
EI入藏号 | 20201708568457
|
EI主题词 | Catalysis
; Catalysts
; Copper
; Free radical reactions
; Ligands
; Stereochemistry
|
EI分类号 | Copper:544.1
; Chemistry:801
; Physical Chemistry:801.4
; Chemical Reactions:802.2
; Chemical Agents and Basic Industrial Chemicals:803
; Chemical Products Generally:804
; Organic Compounds:804.1
|
ESI学科分类 | CHEMISTRY
|
Scopus记录号 | 2-s2.0-85077404451
|
来源库 | Scopus
|
引用统计 |
被引频次[WOS]:468
|
成果类型 | 期刊论文 |
条目标识符 | http://kc.sustech.edu.cn/handle/2SGJ60CL/60826 |
专题 | 理学院_化学系 前沿与交叉科学研究院 深圳格拉布斯研究院 |
作者单位 | 1.Shenzhen Grubbs Institute and Department of Chemistry,Southern University of Science and Technology,Shenzhen,518055,China 2.Academy for Advanced Interdisciplinary Studies,Southern University of Science and Technology,Shenzhen,518055,China |
第一作者单位 | 化学系; 深圳格拉布斯研究院; 前沿与交叉科学研究院 |
通讯作者单位 | 化学系; 深圳格拉布斯研究院 |
第一作者的第一单位 | 化学系; 深圳格拉布斯研究院 |
推荐引用方式 GB/T 7714 |
Li,Zhong Liang,Fang,Gui Chun,Gu,Qiang Shuai,et al. Recent advances in copper-catalysed radical-involved asymmetric 1,2-difunctionalization of alkenes[J]. CHEMICAL SOCIETY REVIEWS,2019,49(1):32-48.
|
APA |
Li,Zhong Liang,Fang,Gui Chun,Gu,Qiang Shuai,&Liu,Xin Yuan.(2019).Recent advances in copper-catalysed radical-involved asymmetric 1,2-difunctionalization of alkenes.CHEMICAL SOCIETY REVIEWS,49(1),32-48.
|
MLA |
Li,Zhong Liang,et al."Recent advances in copper-catalysed radical-involved asymmetric 1,2-difunctionalization of alkenes".CHEMICAL SOCIETY REVIEWS 49.1(2019):32-48.
|
条目包含的文件 | ||||||
文件名称/大小 | 文献类型 | 版本类型 | 开放类型 | 使用许可 | 操作 | |
chem-soc-rev-2020.pd(2573KB) | -- | -- | 限制开放 | -- |
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