题名 | Highly stable single Pt atomic sites anchored on aniline-stacked graphene for hydrogen evolution reaction |
作者 | |
通讯作者 | Gu, Meng; Liu, Jianhong; Sun, Xueliang |
发表日期 | 2019-03
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DOI | |
发表期刊 | |
ISSN | 1754-5692
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EISSN | 1754-5706
|
卷号 | 12期号:3页码:1000-1007 |
摘要 | Developing efficient and cost-effective electrocatalysts for hydrogen evolution reaction (HER) is highly desired for the hydrogen economy. In this study, we developed a facile microwave reduction method to synthesize single Pt atoms anchored on aniline-stacked graphene (Pt SASs/AG) with outstanding HER performance. Pt SASs/AG presents excellent HER activity with = 12 mV at 10 mA cm(-2) and a mass current density of 22400 Ag-Pt(-1) at = 50 mV, which is 46 times higher than that of commercial 20 wt% Pt/C. Moreover, the Pt SASs/AG catalyst is highly active and more stable than Pt/C. X-ray absorption fine spectroscopy and density functional theory calculations demonstrated that the coordination of atomically isolated Pt with the nitrogen of aniline optimized the electronic structure of Pt and the hydrogen adsorption energy, eventually promoting HER activity. This study provides a new avenue for the development of single-atom Pt electrocatalysts with high activity and stability. |
相关链接 | [来源记录] |
收录类别 | |
语种 | 英语
|
重要成果 | ESI高被引
|
学校署名 | 通讯
|
资助项目 | Major Programs for Science and Technology Development of Shenzhen[XCL201110060]
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WOS研究方向 | Chemistry
; Energy & Fuels
; Engineering
; Environmental Sciences & Ecology
|
WOS类目 | Chemistry, Multidisciplinary
; Energy & Fuels
; Engineering, Chemical
; Environmental Sciences
|
WOS记录号 | WOS:000462661900012
|
出版者 | |
EI入藏号 | 20191206661639
|
EI主题词 | Aniline
; Atoms
; Cost effectiveness
; Density functional theory
; Electrocatalysts
; Electronic structure
; Graphene
; X ray absorption
|
EI分类号 | Electromagnetic Waves:711
; Nanotechnology:761
; Chemical Operations:802.3
; Chemical Agents and Basic Industrial Chemicals:803
; Chemical Products Generally:804
; Organic Compounds:804.1
; Industrial Economics:911.2
; Atomic and Molecular Physics:931.3
|
来源库 | Web of Science
|
引用统计 |
被引频次[WOS]:386
|
成果类型 | 期刊论文 |
条目标识符 | http://kc.sustech.edu.cn/handle/2SGJ60CL/26352 |
专题 | 工学院_材料科学与工程系 公共分析测试中心 |
作者单位 | 1.Shenzhen Univ, Coll Chem & Environm Engn, Shenzhen 518060, Peoples R China 2.Univ Western Ontario, Dept Mech & Mat Engn, London, ON N6A 5B9, Canada 3.Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen 518055, Peoples R China 4.Xiangtan Univ, Sch Mat Sci & Engn, Xiangtan 411105, Peoples R China 5.South Univ Sci & Technol China, Mat Characterizat & Preparat Ctr, Shenzhen 518055, Peoples R China |
通讯作者单位 | 材料科学与工程系 |
推荐引用方式 GB/T 7714 |
Ye, Shenghua,Luo, Feiyan,Zhang, Qianling,et al. Highly stable single Pt atomic sites anchored on aniline-stacked graphene for hydrogen evolution reaction[J]. Energy & Environmental Science,2019,12(3):1000-1007.
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APA |
Ye, Shenghua.,Luo, Feiyan.,Zhang, Qianling.,Zhang, Pingyu.,Xu, Tingting.,...&Sun, Xueliang.(2019).Highly stable single Pt atomic sites anchored on aniline-stacked graphene for hydrogen evolution reaction.Energy & Environmental Science,12(3),1000-1007.
|
MLA |
Ye, Shenghua,et al."Highly stable single Pt atomic sites anchored on aniline-stacked graphene for hydrogen evolution reaction".Energy & Environmental Science 12.3(2019):1000-1007.
|
条目包含的文件 | 条目无相关文件。 |
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