中文版 | English
题名

A robust aqueous-processable polymer binder for long-life, high-performance lithium sulfur battery

作者
通讯作者Deng, Yonghong
发表日期
2019-09
DOI
发表期刊
ISSN
2405-8297
卷号21页码:61-68
摘要
The development of lithium sulfur batteries (LSBs) has significantly suffered from the shuttle of lithium polysulfides (LiPS) and drastic volume change of the active materials during cycling processes. The eco-friendly manufacturing of electrodes based on aqueous slurries is highly desirable for practical applications. To address these challenging issues, a novel aqueous-processable polymer, chitosan sulfate ethylamide glycinamide (CSEG), has been developed as the binder for sulfur cathode. The dual-amide structures endow the CSEG with superior LiPS-trapping capability to impede the diffusion and shuttle of LiPS in electrolyte. The CSEG-based sulfur cathodes demonstrate remarkable cycling performances at 1 C for 700 cycles and 6 C for 450 cycles, with only 0.049%, 0.0895% capacity fading per cycle, respectively. More importantly, the cathode achieves excellent rate performance with a capacity of 194.4 mAh g(-1) at an ultrahigh current density of 40.26 mA cm(-2) (20 C), which takes only 21 s for one charge or discharge process. The electrochemical performance of the novel CSEG binder, as demonstrated in this work, is superior to all previously reported aqueous-processable binders for sulfur cathode. Such a breakthrough will greatly improve the development of eco-friendly sulfur cathode, paving new ways for the practical application of next-generation LSBs.
关键词
相关链接[来源记录]
收录类别
SCI ; EI
语种
英语
学校署名
第一 ; 通讯
资助项目
Fundamental Research Foundation of Shenzhen[JCYJ20170412153424150]
WOS研究方向
Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目
Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号
WOS:000484341600006
出版者
EI入藏号
20192907206804
EI主题词
Amides ; Binders ; Cathodes ; Electric discharges ; Electrolytes ; Environmental protection ; Lithium batteries ; Lithium compounds ; Polymers ; Sulfur compounds
EI分类号
Environmental Impact and Protection:454.2 ; Electricity: Basic Concepts and Phenomena:701.1 ; Primary Batteries:702.1.1 ; Chemical Agents and Basic Industrial Chemicals:803 ; Organic Compounds:804.1 ; Polymeric Materials:815.1
来源库
Web of Science
引用统计
被引频次[WOS]:61
成果类型期刊论文
条目标识符http://kc.sustech.edu.cn/handle/2SGJ60CL/25239
专题工学院_材料科学与工程系
前沿与交叉科学研究院
作者单位
1.Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen 518055, Peoples R China
2.South China Univ Technol, Res Inst Mat Sci, Guangzhou 510640, Guangdong, Peoples R China
3.Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB T6G 1H9, Canada
4.Univ Alberta, Dept Mech Engn, Edmonton, AB T6G 1H9, Canada
5.Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Shenzhen 518055, Peoples R China
第一作者单位材料科学与工程系
通讯作者单位材料科学与工程系
第一作者的第一单位材料科学与工程系
推荐引用方式
GB/T 7714
Yi, Huan,Lan, Tu,Yang, Yu,et al. A robust aqueous-processable polymer binder for long-life, high-performance lithium sulfur battery[J]. Energy Storage Materials,2019,21:61-68.
APA
Yi, Huan.,Lan, Tu.,Yang, Yu.,Zeng, Hongbo.,Zhang, Tian.,...&Deng, Yonghong.(2019).A robust aqueous-processable polymer binder for long-life, high-performance lithium sulfur battery.Energy Storage Materials,21,61-68.
MLA
Yi, Huan,et al."A robust aqueous-processable polymer binder for long-life, high-performance lithium sulfur battery".Energy Storage Materials 21(2019):61-68.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可 操作
Yi-2019-A robust aqu(1246KB)----限制开放--
个性服务
原文链接
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
导出为Excel格式
导出为Csv格式
Altmetrics Score
谷歌学术
谷歌学术中相似的文章
[Yi, Huan]的文章
[Lan, Tu]的文章
[Yang, Yu]的文章
百度学术
百度学术中相似的文章
[Yi, Huan]的文章
[Lan, Tu]的文章
[Yang, Yu]的文章
必应学术
必应学术中相似的文章
[Yi, Huan]的文章
[Lan, Tu]的文章
[Yang, Yu]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
[发表评论/异议/意见]
暂无评论

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。

Baidu
map