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题名

Metal chelation based supramolecular self-assembly enables a high-performance organic anode for lithium ion batteries

作者
通讯作者Wang,Jun; Wang,Chaoyang; Deng,Yonghong
发表日期
2020-10-28
DOI
发表期刊
ISSN
1385-8947
EISSN
1873-3212
卷号413
摘要

The rising pursuit for green rechargeable energy storage devices desires novel electrode materials with cost-effective, environmental-friendly properties besides high electrochemical performance, boosting the rapid development of organic electrodes. However, the organic electrode materials in most reports can hardly be used in the real applications due to relatively poor electrochemical performance. Herein, by utilizing a smart supramolecular self-assembly between metal ions and ligands, we facilely chelate the rhodizonic acid disodium salt (RA) using ferric ions and generate a novel organic anode material (RAFe) for the first time. The strong chelation interaction between ferric ions and rhodizonic acid changes its initial structure and characteristics, enabling the obtained organic RAFe compound with outstanding electrochemical performance as anode for lithium ion batteries (LIB), which includes high reversible capacity (1283 mAh/g at 0.1A/g), excellent rate capability, long cycling stability (0.5 A/g over 300 cycles with a capacity retention of 90.76%, i.e. 0.03% decay per cycle). Even at a high mass loading of 4.0 mg/cm, this organic anode can still deliver a capacity over 1000 mAh/g with the specific area capacity of 4.09 mAh/cm at 0.2 A/g, and maintains it over 92.4% after 100 cycles. Apart from offering a promising organic anode material, this work also broadens the application of metal chelation interaction based supramolecular self-assembly in energy storage territory which will inspire the preparation of other high-performance organic materials for advanced LIBs.

关键词
相关链接[Scopus记录]
收录类别
SCI ; EI
语种
英语
学校署名
第一 ; 通讯
资助项目
KeyArea Research and Development Program of Guangdong Province["2020B090919001","2019B090908001"] ; National Key R&D Program of China[2018YFB0104300] ; Science and Technology Program of Guangzhou[202002030307] ; Guangdong Basic and Applied Basic Research Foundation[2019A1515010595] ; Guangdong Provincial Key Laboratory of Energy Materials for Electric Power[2018B030322001]
WOS研究方向
Engineering
WOS类目
Engineering, Environmental ; Engineering, Chemical
WOS记录号
WOS:000640423800003
出版者
EI入藏号
20204509452996
EI主题词
Electrochemical electrodes ; Chelation ; Metals ; Energy storage ; Self assembly ; Storage (materials) ; Lithium-ion batteries ; Metal ions ; Cost effectiveness ; Supramolecular chemistry
EI分类号
Energy Storage:525.7 ; Metallurgy:531.1 ; Storage:694.4 ; Electron Tubes:714.1 ; Physical Chemistry:801.4 ; Chemical Reactions:802.2 ; Industrial Economics:911.2 ; Materials Science:951
ESI学科分类
ENGINEERING
Scopus记录号
2-s2.0-85094880248
来源库
Scopus
引用统计
被引频次[WOS]:11
成果类型期刊论文
条目标识符http://kc.sustech.edu.cn/handle/2SGJ60CL/209241
专题工学院_材料科学与工程系
前沿与交叉科学研究院
作者单位
1.Department of Materials Science & Engineering,Academy for Advanced Interdisciplinary Studies,Guangdong Provincial Key Laboratory of Energy Materials for Electric Power,Southern University of Science and Technology,Shenzhen,518055,China
2.Research Institute of Materials Science,South China University of Technology,Guangzhou,510640,China
3.College of Materials and Energy,Guangdong Laboratory for Lingnan Modern Agriculture,South China Agricultural University,Guangzhou,510642,China
4.Department of Chemical and Materials Engineering,University of Alberta,Edmonton,T6G 1H9,Canada
第一作者单位材料科学与工程系;  前沿与交叉科学研究院
通讯作者单位材料科学与工程系;  前沿与交叉科学研究院
第一作者的第一单位材料科学与工程系;  前沿与交叉科学研究院
推荐引用方式
GB/T 7714
Zhang,Guangzhao,Wang,Hui,Deng,Xiaolan,et al. Metal chelation based supramolecular self-assembly enables a high-performance organic anode for lithium ion batteries[J]. CHEMICAL ENGINEERING JOURNAL,2020,413.
APA
Zhang,Guangzhao.,Wang,Hui.,Deng,Xiaolan.,Yang,Yu.,Zhang,Tian.,...&Deng,Yonghong.(2020).Metal chelation based supramolecular self-assembly enables a high-performance organic anode for lithium ion batteries.CHEMICAL ENGINEERING JOURNAL,413.
MLA
Zhang,Guangzhao,et al."Metal chelation based supramolecular self-assembly enables a high-performance organic anode for lithium ion batteries".CHEMICAL ENGINEERING JOURNAL 413(2020).
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